Electrochemistry of Flavonolignans in Acetonitrile and Dimethylsulfoxide

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F14%3A00428757" target="_blank" >RIV/61388971:_____/14:00428757 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/14:00428757
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Electrochemistry of Flavonolignans in Acetonitrile and Dimethylsulfoxide
Original language description
This study is focused on investigation of oxidation pathways of silybin and 2,3-dehydrosilybin in nonaqueous solutions. The oxidation mechanism of both flavonolignans differs and depends strongly on their chemical structure. The cyclic voltammetry, UV/Vis and IR spectroelectrochemistry were used for identification of electrooxidation (semiquinone) intermediates. HPLC with diode array detection was applied for identification of oxidation and degradation products. Molecular orbital calculations supported the experimental findings.
Czech name
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Czech description
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Project
<a href="/en/project/GAP207%2F11%2F0629" target="_blank" >GAP207/11/0629: Thiazoline inhibitors of ?-N-acetylhexosaminidase based on new, non-natural substrates.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection
Sborník přednášek mezinárodní odborné konference XXXIV. Moderní Elektrochemické Metody
ISBN
978-80-905221-2-1
ISSN
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e-ISSN
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Number of pages
5
Pages from-to
161-165
Publisher name
Best Servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 19, 2014
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
000353446900035

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