Nucleophilic Tetrafluoroethylation Employing in Situ Formed Organomagnesium Reagents

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F16%3A00472524" target="_blank" >RIV/61388971:_____/16:00472524 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/16:00467402
Result on the web
<a href="http://dx.doi.org/10.1021/acs.orglett.6b02890" target="_blank" >http://dx.doi.org/10.1021/acs.orglett.6b02890</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.orglett.6b02890" target="_blank" >10.1021/acs.orglett.6b02890</a>

Result language
angličtina
Original language name
Nucleophilic Tetrafluoroethylation Employing in Situ Formed Organomagnesium Reagents
Original language description
Tetrafluoroalkyl bromides are metalated with equi-molar iPrMgCl.LiCl (Turbo Grignard) to form organomagnesium compounds which are stable at low temperatures and react with various electrophiles (aldehydes, ketones, CO2, cyclic sulfate and sulfamidate, N-sulfonylimines, nitrone, chlorophosphate, nonaflyl azide) to afford novel functionalized tetrafluoroethylene-containing products. Ease of operation, excellent selectivity, high nucleophilicity, and enhanced stability of the reactive species together with a broad substrate scope comprise a highly attractive nudeophilic tetrafluoroethylation protocol affording unique synthetic building blocks.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
EE - Microbiology, virology
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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