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Phenolic Iron Complexes Protect Glacier Ice Algae (Zygnematophyceae) Against Excessive UV and VIS Irradiation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F25%3A00637889" target="_blank" >RIV/61388971:_____/25:00637889 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/25:10500351 RIV/00216208:11310/25:10500351

  • Result on the web

    <a href="https://enviromicro-journals.onlinelibrary.wiley.com/doi/10.1111/1758-2229.70149" target="_blank" >https://enviromicro-journals.onlinelibrary.wiley.com/doi/10.1111/1758-2229.70149</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1111/1758-2229.70149" target="_blank" >10.1111/1758-2229.70149</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Phenolic Iron Complexes Protect Glacier Ice Algae (Zygnematophyceae) Against Excessive UV and VIS Irradiation

  • Original language description

    Melting glacier surfaces are increasingly affected by blooms of psychrophilic microalgae, which darken the ice and lower its albedo, accelerating melting. These microalgae contain distinct vacuoles filled with brownish pigments that were earlier described as the unusual plant phenol purpurogallin. Recently, we discovered so far unreported, large amounts of iron dissolved in aqueous extracts of the glacier ice algae Ancylonema alaskanum. Since the vacuole content was very dark but the chromatographically isolated, aforementioned phenol was only yellowish, a putative complexation of iron with purpurogallin was assumed to be the reason. Application of several protocols, including Raman microscopy on both living cells and extracts, provided strong evidence that this microalga sequesters iron and forms organic metal complexes. Consequently, substantial amounts of so far uncharacterised Fe-complexes of purpurogallin are inferred to be present in Ancylonema, and that putative polymerisation of this compound impeded an earlier analytical discovery. This finding holds significant ecological implications for cold regions. The pigmentation not only enhances the tolerance of glacier ice algae to excessive UV and visible radiation but also influences our current understanding of the biochemical iron cycle in cryosphere-dominated polar and alpine regions. Further downstream consequences of this biological iron source remain to be elucidated.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10606 - Microbiology

Result continuities

  • Project

    <a href="/en/project/GA24-10019S" target="_blank" >GA24-10019S: Snow algae blooms under climate change: unravelling the diversity patterns and seasonal dynamics to understand their current and future distribution</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Environmental Microbiology Reports

  • ISSN

    1758-2229

  • e-ISSN

    1758-2229

  • Volume of the periodical

    17

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    e70149

  • UT code for WoS article

    001527217900001

  • EID of the result in the Scopus database

    2-s2.0-105010892157