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Thermal behaviour of Ni-Mn layered double hydroxide and characterization of formed oxides.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F03%3A50033044" target="_blank" >RIV/61388980:_____/03:50033044 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/03:00020156

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermal behaviour of Ni-Mn layered double hydroxide and characterization of formed oxides.

  • Original language description

    Thermal behaviour of the Ni-Mn layered double hydroxide (LDH) with Ni/Mn molar ratio equal to 2 prepared by coprecipitation was studied in temperature range 200-1100 degreesC by thermal analysis (TG/DTA/EGA), powder X-ray diffraction (XRD), infrared spectroscopy and voltammetry of microparticles. A loss of interlayer water (dehydration) and sample decomposition accompanied by H2O and CO2 evolution were observed at 175 and 265 degreesC, respectively. Thermal decomposition of Ni-Mn LDH resulted in formation of a predominantly amorphous. mixture of oxides. A relatively high content of amorphous part was observed in samples heated at 200-500 degreesC. The onset of Ni6MnO8 crystallization was detected by XRD in samples heated at 300 degreesC. Together withNi6MnO8, NiMnO3 was detected by XRD in samples heated at 500 degreesC. According to the voltammetry, the further reconstruction of oxides took place above 600 degreesC. NiMnO3 and Ni6MnO8 were converted to spinel (Ni,Mn)(3)O-4 occurring t

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Solid State Sciences

  • ISSN

    1293-2558

  • e-ISSN

  • Volume of the periodical

    5

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    1019-1026

  • UT code for WoS article

  • EID of the result in the Scopus database