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Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F05%3A00021491" target="_blank" >RIV/61388980:_____/05:00021491 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8

  • Original language description

    Treatment of a solution of excess PCl3 and PS (PS = "proton sponge" = 1,8-dimethylamino naphthalene) with arachno-4-CB8H14 (1) in CH2Cl2, followed by hydrolysis of the reaction mixture, resulted in the isolation of the eleven-vertex diphosphacarbaboranenido-7,8,9-P2CB8H10 (2) (yield 34percent) as the main product. Other products isolated from this reaction were the phosphacarboranes nido-7,8,9,10-P3CB7H8 (3) (yield 5percent) and closo-2,1-PCB8H9 (4) (yield 15percent). Compound 2 can be deprotonated byPS in CH2O2 or NaH in diethyl ether to give the [nido-7,8,9-P2CB8H9](-) (2(-)) anion, which gives back the original compound, 2, upon re-protonation.

  • Czech name

    Difosfakarbollidová analoga (C5H5)- aniontu: Isolace nido di-a trifosphakarboranů 7,8,9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8

  • Czech description

    Reakce mezi PCl3 and PS (PS = "protonová houba" = 1,8-bis-dimethylaminonaftalen) a monokarbaboranem arachno-4-CB8H14 vedla k isolaci jedenáctivrcholových fosfakarboranů nido-7,8,9-P2CB8H10 a nido-7,8,9,10-P3CB7H8. Jsou diskutovány i některé základní reakce těchto sloučenin.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F05%2F2646" target="_blank" >GA203/05/2646: Derivatization of ferratricarbollide</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    44

  • Issue of the periodical within the volume

    16

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    5826-5832

  • UT code for WoS article

  • EID of the result in the Scopus database