An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F05%3A00029913" target="_blank" >RIV/61388980:_____/05:00029913 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
Original language description
Cage closure, together with the loss of two boron vertices, of [2,5-(eta(5)-C5Me5)(2)-10-Me-mu-2,5-H-)nido-2,5,1-Rh,CB6H8] (1) using an approximately molar equivalent of elemental iodine and excess triethylamine results in the formation of a new species[1,2-(eta 5-C5Me5)2-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (2), which is characterized by multinuclear NMR spectroscopy, mass spectrometry, and single-crystal X-ray crystallography. The formation Of Compound 2 involves the elimination of a {B2CH3) moiety from I and an iodination of the single carbon vertex.
Czech name
Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
Czech description
Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
690
Issue of the periodical within the volume
21-22
Country of publishing house
CH - SWITZERLAND
Number of pages
4
Pages from-to
4967-4970
UT code for WoS article
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EID of the result in the Scopus database
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