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Electrophilic halogenation of nido-5,6-C2B8H12

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F06%3A00050975" target="_blank" >RIV/61388980:_____/06:00050975 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrophilic halogenation of nido-5,6-C2B8H12

  • Original language description

    Room-temperature chlorination of the dicarbaborane nido-5,6-C2B8H12 ( 1) with CCl4 in the presence of anhydrous AlCl3 yielded a mixture of 7-Cl-5,6-C2B8H11 (7-Cl-1) ( yield 34 percent), 4-Cl-5,6-C2B8H11 (4- Cl-1) ( yield 20 percent), 3-Cl-5,6-C2B8H11 (3-Cl-1) ( yield 21 percent), and 3,4-Cl-2-5,6- C2B8H10 (3,4- Cl-2- 1) ( yield 26 percent), while a trisubstituted derivative, 3,4,7-Cl-3- 5,6-C2B8H9 (3,4,7-Cl-3- 1) ( yield 80 percent), was isolated as a sole product at reflux.

  • Czech name

    Elektrofilní halogenace nido-5,6- C2B8H12

  • Czech description

    Elektrofilní halogenace nido-5,6- C2B8H12.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F05%2F2646" target="_blank" >GA203/05/2646: Derivatization of ferratricarbollide</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    71

  • Issue of the periodical within the volume

    11-12

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    7

  • Pages from-to

    1549-1556

  • UT code for WoS article

  • EID of the result in the Scopus database