Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F07%3A00097276" target="_blank" >RIV/61388980:_____/07:00097276 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes
Original language description
The metal-to-heteroborane bonding sphere of 1 is fluxional, with a Delta G(double dagger) value of 48.4 kJ mol(-1). DFT calculations on the model compounds [8,8-(PH3)(2)-nido-8,7-RhNB9H11] (1a) and [8,8-(PH3)(2)-nido-8,7-RhSB9H10] (4a) have been carriedout to define the fluxional process and the intermediates involved.
Czech name
Polyedrická metalaheteroboranová chemie. Syntéza, spektroskopie, struktura a dynamika jedenáctivrcholových RhNB9 a PtCB9 metala heteroboranů
Czech description
Je popsán vznik jedenáctivrcholových komplexů rhodia a platiny, které v molekule obsahují desetivrcholový azaboranový a karbaboranový klastr jako ligand vázaný na kov.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
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Volume of the periodical
-
Issue of the periodical within the volume
27
Country of publishing house
GB - UNITED KINGDOM
Number of pages
13
Pages from-to
2885-2897
UT code for WoS article
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EID of the result in the Scopus database
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