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The gas-phase structure of 1-selena-closo-dodecaborane(11), 1-SeB11H11, determined by the concerted use of electron diffraction and computational methods

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F08%3A00319082" target="_blank" >RIV/61388980:_____/08:00319082 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The gas-phase structure of 1-selena-closo-dodecaborane(11), 1-SeB11H11, determined by the concerted use of electron diffraction and computational methods

  • Original language description

    The accuracy of the experimental structure, as well as that calculated at the MP2/ 962(d) level, has been gauged by comparison of the B-11 chemical shifts (calculated at two different gauge-including atomic orbitals (GIAO) levels) with experimental NMR values. The inclusion of electron correlation in the magnetic property calculations (GIAO-MP2) gave superior results to those carried out using GIAO-Hartree-Fock.

  • Czech name

    Plynná fáze struktury 1-selen-kloso-dodekaborane(11), 1-SeB11H11, předurčený použitím elektronové difrakce a výpočtových metod

  • Czech description

    Přesnost experimentální struktury, právě tak jako vypočítaný v MP2/ 962(d) úrovni, byl zkušební přístroj srovnáním posunů B-11 chemikálií (vypočítaný včetně atomické orbitální (GIAO) úrovně) s experimentálními NMR hodnotami.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Dalton Transactions

  • ISSN

    1477-9226

  • e-ISSN

  • Volume of the periodical

    -

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    5

  • Pages from-to

  • UT code for WoS article

    000251673200017

  • EID of the result in the Scopus database