Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F08%3A00340425" target="_blank" >RIV/61388980:_____/08:00340425 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+)

Original language description

The benzene complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3a) was synthesized by the photochemical reaction of [(eta(5)-C6H7)Fe(eta-C6H6)](+) (1) with the anion [7-(BuNH)-N-t-7,8,9-C3B8H10](-) followed by the treatment of ferracarborane 1-(eta(5)-C6H7)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(eta-C6R6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3b-e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Russian Chemical Bulletin

ISSN

1066-5285

e-ISSN

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Volume of the periodical

57

Issue of the periodical within the volume

11

Country of publishing house

RU - RUSSIAN FEDERATION

Number of pages

4

Pages from-to

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UT code for WoS article

000271939100011

EID of the result in the Scopus database

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