Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F08%3A00341227" target="_blank" >RIV/61388980:_____/08:00341227 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8

Original language description

Treatment of the nido-1-CB8H12 (1) carborane with NaBH, in THF at ambient temperature led to the isolation of the stable [arachno-5-CB8H13](-) (2(-)), which was isolated as Na+[5-CB8H13](-).1.5THF and PPh4+[5-CB8H13](-) in almost quantitative yield.The method gave superior results to those carried out using GIAO-HF when relating the calculated B-11 NMR chemical shifts to experimental data.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemistry - A European Journal

ISSN

0947-6539

e-ISSN

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Volume of the periodical

14

Issue of the periodical within the volume

21

Country of publishing house

DE - GERMANY

Number of pages

5

Pages from-to

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UT code for WoS article

000258092400026

EID of the result in the Scopus database

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