The electrochemical redox processes in methacrylate-based polymer electrolytes II. - Study on microelectrodes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F10%3A00358211" target="_blank" >RIV/61388980:_____/10:00358211 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The electrochemical redox processes in methacrylate-based polymer electrolytes II. - Study on microelectrodes
Original language description
he electrochemical behaviour of ferrocene was studied in different gel polymer electrolytes based on methyl, ethyl and 2-ethoxyethyl methacrylate and compared to the liquid aprotic solution (propylene carbonate). Voltammetric and chronoamperometric measurements on microelectrodes were conducted in order to describe the qualitative as well as quantitative behaviour of ferrocene in different conditions. Heterogeneous electron-transfer rate constants and diffusion coefficients of ferrocene in polymer electrolytes were estimated to be 1.1-7.8 x 10(-3) cm s(-1) and 4-13 x 10(-8) cm(2) s(-1) depending on the electrolyte composition. The influence of the polymer polarity, ferrocene concentration and level of polymer cross-linkage on the kinetics of ferroceneoxidation and its transport was discussed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica acta
ISSN
0013-4686
e-ISSN
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Volume of the periodical
55
Issue of the periodical within the volume
20
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
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UT code for WoS article
000280422800057
EID of the result in the Scopus database
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