Photorelease of triplet and singlet oxygen from dioxygen complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F11%3A00367782" target="_blank" >RIV/61388980:_____/11:00367782 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ccr.2011.06.017" target="_blank" >http://dx.doi.org/10.1016/j.ccr.2011.06.017</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ccr.2011.06.017" target="_blank" >10.1016/j.ccr.2011.06.017</a>

Result language
angličtina
Original language name
Photorelease of triplet and singlet oxygen from dioxygen complexes
Original language description
Photolysis of some dioxygen transition metal complexes leads to the release of oxygen molecules in two electronic states, namely, in the ground triplet state 3?g and the lowest excited singlet state 1?g. The reaction involves electron transfer from the dioxygen moiety to the central metal ion. In the reported cases, the photoreaction of peroxo complexes is activated by ligand-to-metal charge transfer excitation. The mechanism of singlet oxygen photorelease relates to intramolecular energy transfer and differs in principle from the photosensitization process. Consequently, the photorelease can be viewed as a new route to dioxygen activation by spin inversion of the ground state oxygen to singlet oxygen.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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