Magnetic Field Effect on Chemical Compositions of Magnetic Aerosol Particles Synthesized Photochemically from a Gaseous Mixture of Iron Pentacarbonyl and Trimethylsilyl Azide
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F13%3A00422831" target="_blank" >RIV/61388980:_____/13:00422831 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/02786826.2013.829552" target="_blank" >http://dx.doi.org/10.1080/02786826.2013.829552</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/02786826.2013.829552" target="_blank" >10.1080/02786826.2013.829552</a>
Alternative languages
Result language
angličtina
Original language name
Magnetic Field Effect on Chemical Compositions of Magnetic Aerosol Particles Synthesized Photochemically from a Gaseous Mixture of Iron Pentacarbonyl and Trimethylsilyl Azide
Original language description
Under intense UV light irradiation with an Nd:YAG laser at 355nm, a gaseous mixture of iron pentacarbonyl (Fe(CO)(5)) and trimethylsilyl azide (TMSAz) produced aerosol magnetic particles with diameters of 50-100nm. Two photon absorption of TMSAz and Fe(CO)(5) took place efficiently to produce trimethylsilyl nitrene and iron carbonyls (Fe(CO) (n) n = 1-4). In cases where a partial pressure of TMSAz was high, nucleation reactions of aerosol particles proceeded via chemical reactions between trimethylsilylnitrene and two iron carbonyls, resulting in bridging between two iron carbonyls by silyl nitrene. In cases where a partial pressure of TMSAz was low, the nucleation reactions proceeded via chemical reactions between two iron carbonyls, resulting in theformation of di-iron carbonyls with bridging >CO group. Both of these nucleation reactions took place concurrently during aerosol particle formation. From FT-IR spectral change of sedimentary particles produced under an external magnetic
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Aerosol Science and Technology
ISSN
0278-6826
e-ISSN
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Volume of the periodical
47
Issue of the periodical within the volume
11
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
1188-1195
UT code for WoS article
000324459700004
EID of the result in the Scopus database
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