Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F15%3A00442463" target="_blank" >RIV/61388980:_____/15:00442463 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/15:39900102
Result on the web
<a href="http://dx.doi.org/10.1021/om500988z" target="_blank" >http://dx.doi.org/10.1021/om500988z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om500988z" target="_blank" >10.1021/om500988z</a>

Result language
angličtina
Original language name
Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10
Original language description
Room-temperature reaction between nido-5,6-C2B8H12 (1) and elemental iodine in the presence of triethylamine in CH2Cl2 gave the closo-1,6-C2B8H10 (2) dicarbaborane in 85% yield. All the electrophilic halogenation reactions of 2 led exclusively to B(8)-substitution to get a series of 8-X-closo-1,6-C2B8H9 (8X-2) derivatives (where X = Cl, Br, and I). Thermal rearrangements of 2 and 8X-2 at similar to 500-600 degrees C produced closo-1,10-C2B8H10 (3) and a series of halo derivatives 2-X-closo-1,10-C2B8H9 (2X-3), respectively. All the compounds isolated have been characterized by multinuclear (B-11, H-1, and C-13) NMR spectroscopy, mass spectrometry, and elemental analyses, and the structure of 8Br-2 was established by X-ray diffraction study.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F11%2F0705" target="_blank" >GAP207/11/0705: Carborane-modified iron-arene complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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