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10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F16%3A00458229" target="_blank" >RIV/61388980:_____/16:00458229 - isvavai.cz</a>

  • Alternative codes found

    RIV/68378271:_____/16:00458229 RIV/00216275:25310/16:39901213

  • Result on the web

    <a href="http://dx.doi.org/10.1039/C5CE02501J" target="_blank" >http://dx.doi.org/10.1039/C5CE02501J</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/C5CE02501J" target="_blank" >10.1039/C5CE02501J</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers

  • Original language description

    1,10-Dicarboxy-1,10-dicarba-closo-decaborane, a classical dicarboxylate spacer ligand type similar to the prototypical terephthalic acid, proved to be different not only from the latter, but also from its closest relative compound, 1,12-dicarboxy-closo-1,12-dicarbadecaborane, with regard to the topology of its derived PCPs. Highly porous and robust compounds of zinc (rob net) and cobalt (quasi’ pcu) as well as a topologically unexpected copper compound (lvt) define the individuality of the 10-vertex carborane cage as a new fundamental spacer type in PCP chemistry. A combination of a lower steric demand compared to the 12-vertex analogue, a preferred orientation angle of 45° between the carboxylate planes and a moderately low rotation barrier are held responsible for the uniqueness of the 10-vertex analogue.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    CrystEngComm

  • ISSN

    1466-8033

  • e-ISSN

  • Volume of the periodical

    18

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    5

  • Pages from-to

    2036-2040

  • UT code for WoS article

    000372282100001

  • EID of the result in the Scopus database

    2-s2.0-84961768114