10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F16%3A00458229" target="_blank" >RIV/61388980:_____/16:00458229 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/16:00458229 RIV/00216275:25310/16:39901213
Result on the web
<a href="http://dx.doi.org/10.1039/C5CE02501J" target="_blank" >http://dx.doi.org/10.1039/C5CE02501J</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C5CE02501J" target="_blank" >10.1039/C5CE02501J</a>
Alternative languages
Result language
angličtina
Original language name
10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers
Original language description
1,10-Dicarboxy-1,10-dicarba-closo-decaborane, a classical dicarboxylate spacer ligand type similar to the prototypical terephthalic acid, proved to be different not only from the latter, but also from its closest relative compound, 1,12-dicarboxy-closo-1,12-dicarbadecaborane, with regard to the topology of its derived PCPs. Highly porous and robust compounds of zinc (rob net) and cobalt (quasi’ pcu) as well as a topologically unexpected copper compound (lvt) define the individuality of the 10-vertex carborane cage as a new fundamental spacer type in PCP chemistry. A combination of a lower steric demand compared to the 12-vertex analogue, a preferred orientation angle of 45° between the carboxylate planes and a moderately low rotation barrier are held responsible for the uniqueness of the 10-vertex analogue.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
CrystEngComm
ISSN
1466-8033
e-ISSN
—
Volume of the periodical
18
Issue of the periodical within the volume
12
Country of publishing house
GB - UNITED KINGDOM
Number of pages
5
Pages from-to
2036-2040
UT code for WoS article
000372282100001
EID of the result in the Scopus database
2-s2.0-84961768114