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Gamma-radiolytic preparation of multi-component oxides

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F16%3A00459815" target="_blank" >RIV/61388980:_____/16:00459815 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21340/16:00233713

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.radphyschem.2015.11.006" target="_blank" >http://dx.doi.org/10.1016/j.radphyschem.2015.11.006</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.radphyschem.2015.11.006" target="_blank" >10.1016/j.radphyschem.2015.11.006</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Gamma-radiolytic preparation of multi-component oxides

  • Original language description

    The preparation of solid precursors to Zn1-XCdXO and (Lu,Y)(3)Al5O12:Ce induced by Co-60 gamma-ray irradiation of aqueous solutions containing soluble metal salts and ammonium formate is presented: Due to the irradiation, crystalline zinc carbonate hydroxide Zn-4(CO3)(OH)(6). H2O or amorphous carbonates of Lu, Y and Al were formed in the solutions. After calcination at 500 degrees C, the agglomerated phase-pure Zn1-XCdXO with crystallite size about 50 nm was obtained if the Cd concentration in solutions remained below 16 M% (with respect to Zn) with x being up to 0.035. The solid precursors to garnets contained the intended concentration of all elements, according to X-ray fluorescence analysis. After calcination at 1200 degrees C in mild vacuum, the respective phase-pure garnets with crystallite size 100 nm or their solid solution were produced when the Ce dopation was kept below 2 M% (with respect to rare-earth metals). The Ce solubility in the garnet lattice was estimated as 1-2 M% at the calcination conditions used.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA13-09876S" target="_blank" >GA13-09876S: Inorganic nanoscintillators: novel synthesis and size-dependent characteristics.</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Radiation Physics and Chemistry

  • ISSN

    0969-806X

  • e-ISSN

  • Volume of the periodical

    124

  • Issue of the periodical within the volume

    JUL

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    68-74

  • UT code for WoS article

    000375736200014

  • EID of the result in the Scopus database

    2-s2.0-84977900530