Open-face alkylation of the 8-R-nido-7,8,9-C3B8H11 tricarbollides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F16%3A00463508" target="_blank" >RIV/61388980:_____/16:00463508 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/16:39901652 RIV/00216208:11310/16:10325336
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2016.08.001" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2016.08.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2016.08.001" target="_blank" >10.1016/j.jorganchem.2016.08.001</a>
Alternative languages
Result language
angličtina
Original language name
Open-face alkylation of the 8-R-nido-7,8,9-C3B8H11 tricarbollides
Original language description
Sequential methylation of the 8-R-nido-7,8,9-C3B8H11 tricarbollides (R = Ph, p-tol and 2-naphthyl (2-naph)) in the presence of NaH in THF proceeds on the open-face B(10,11) positions to generate mono and dimethyl derivatives, 8-R-nido-7,8,9-C3B8H10-10-Me and 8-R-nido-7,8,9-C3B8H9-10,11-Me2. To demonstrate the general character of the alkylation procedure, B-dialkyl derivatives 8-Ph-nido-7,8,9-C3B8H9-10,11-R1 2 (R1 = C3H5 (All) and CH2Ph) were prepared via analogous alkylation of 8-Ph-nido-7,8,9-C3B8H11 with allyl and benzyl bromides. The structures were substantiated by multinuclear (11B, 1H and 13C) NMR spectroscopy and that of 8-Ph-nido-7,8,9-C3B8H9-10,11-Me2 was determined by an X-ray diffraction analysis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA16-01618S" target="_blank" >GA16-01618S: Ten-vertex dicarbaborane molecular assemblies via alkylation</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
822
Issue of the periodical within the volume
NOV
Country of publishing house
CH - SWITZERLAND
Number of pages
5
Pages from-to
80-84
UT code for WoS article
000385517600012
EID of the result in the Scopus database
2-s2.0-84983514192