Tetranuclear Copper(I) Iodide Complexes: A New Class of X-ray Phosphors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F17%3A00474175" target="_blank" >RIV/61388980:_____/17:00474175 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/17:00474175 RIV/68407700:21340/17:00314024
Result on the web
<a href="http://dx.doi.org/10.1021/acs.inorgchem.7b00240" target="_blank" >http://dx.doi.org/10.1021/acs.inorgchem.7b00240</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.7b00240" target="_blank" >10.1021/acs.inorgchem.7b00240</a>
Alternative languages
Result language
angličtina
Original language name
Tetranuclear Copper(I) Iodide Complexes: A New Class of X-ray Phosphors
Original language description
We report intensive visible light radioluminescence upon X-ray irradiation of archetypal tetranuclear copper(I) iodide complexes containing triphenylphosphine or pyridine ligands in the solid state. These properties, attractive for the design of X-ray responsive materials, can be attributed to the heavy {Cu4I4} cubane-like core, the absence of oxygen quenching of the emissive triplet states, and the high photoluminescence quantum yields. Radioluminescence originates from the same emissive triplet states as those produced by ultraviolet excitation as confirmed by the observed radioluminescence thermochromism. The radioluminescence properties are also preserved after incorporation of these complexes into polystyrene films, making them appealing for the development of plastic scintillators.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
4609-4614
UT code for WoS article
000399625600041
EID of the result in the Scopus database
2-s2.0-85018510098