MCM-41 support for ultrasmall gamma-Fe2O3 nanoparticles for H2S removal

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F17%3A00479317" target="_blank" >RIV/61388980:_____/17:00479317 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11310/17:10364777

Result on the web

<a href="http://dx.doi.org/10.1039/C7TA03652C" target="_blank" >http://dx.doi.org/10.1039/C7TA03652C</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C7TA03652C" target="_blank" >10.1039/C7TA03652C</a>

Result language

angličtina

Original language name

MCM-41 support for ultrasmall gamma-Fe2O3 nanoparticles for H2S removal

Original language description

MCM-41 is proposed to build mesostructured Fe2O3-based sorbents as an alternative to other silica or alumina supports for mid-temperature H2S removal. MCM-41 was synthesized as micrometric (MCM41_M) and nanometric (MCM41_N) particles and impregnated through an efficient two-solvent (hexane-water) procedure to obtain the corresponding gamma-Fe2O3@MCM-41 composites. The active phase is homogeneously dispersed within the 2 nm channels in the form of ultrasmall maghemite nanoparticles assuring a high active phase reactivity. The final micrometric (Fe_MCM41_M) and nanometric (Fe_MCM41_N) composites were tested as sorbents for hydrogen sulphide removal at 300 degrees C and the results were compared with a reference sorbent (commercial unsupported ZnO) and an analogous silica-based sorbent (Fe_SBA15). MCM-41 based sorbents, having the highest surface areas, showed superior performances that were retained after the first sulphidation cycle. Specifically, the micrometric sorbent (Fe_MCM41_M) showed a higher SRC value than the nanometric one (Fe_MCM41_N), due to the low stability of the nanosized particles over time caused by their high reactivity. Furthermore, the low regeneration temperature (300-350 degrees C), besides the high removal capacity, renders MCM41-based systems an alternative class of regenerable sorbents for thermally efficient cleaning up processes in Integrated Gasification Combined Cycles (IGCC) systems.n

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of materials chemistry A

ISSN

2050-7488

e-ISSN

—

Volume of the periodical

5

Issue of the periodical within the volume

41

Country of publishing house

GB - UNITED KINGDOM

Number of pages

11

Pages from-to

21688-21698

UT code for WoS article

000413734800010

EID of the result in the Scopus database

2-s2.0-85032383771