Host-Guest Chemistry of Carboranes: Synthesis of Carboxylate Derivatives and Their Binding to Cyclodextrins
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F18%3A00493265" target="_blank" >RIV/61388980:_____/18:00493265 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/18:10375970
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201802134" target="_blank" >http://dx.doi.org/10.1002/chem.201802134</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201802134" target="_blank" >10.1002/chem.201802134</a>
Alternative languages
Result language
angličtina
Original language name
Host-Guest Chemistry of Carboranes: Synthesis of Carboxylate Derivatives and Their Binding to Cyclodextrins
Original language description
Polyhedral carboxymethyl carborane (C2B10H12) derivatives, including mono- and disubstituted o-, m-, and p-isomers, have been synthesized. Supramolecular host-guest complexation of these derivatives with cyclodextrins (CDs, namely, alpha-, beta-, and gamma-CD) has been investigated in water. The globular structure of the carborane binding moiety and its hydrophobic character qualify it as an ideal recognition site to form stable inclusion complexes with macrocyclic host molecules in aqueous solution. The measured binding affinities for the carborane derivatives were in the millimolar range (K-a=10(3)-10(4)m(-1)) with differently sized CDs, and preferential binding to beta-CD.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
24
Issue of the periodical within the volume
49
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
12970-12975
UT code for WoS article
000443382500028
EID of the result in the Scopus database
2-s2.0-85052611031