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Host-Guest Chemistry of Carboranes: Synthesis of Carboxylate Derivatives and Their Binding to Cyclodextrins

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F18%3A00493265" target="_blank" >RIV/61388980:_____/18:00493265 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/18:10375970

  • Result on the web

    <a href="http://dx.doi.org/10.1002/chem.201802134" target="_blank" >http://dx.doi.org/10.1002/chem.201802134</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chem.201802134" target="_blank" >10.1002/chem.201802134</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Host-Guest Chemistry of Carboranes: Synthesis of Carboxylate Derivatives and Their Binding to Cyclodextrins

  • Original language description

    Polyhedral carboxymethyl carborane (C2B10H12) derivatives, including mono- and disubstituted o-, m-, and p-isomers, have been synthesized. Supramolecular host-guest complexation of these derivatives with cyclodextrins (CDs, namely, alpha-, beta-, and gamma-CD) has been investigated in water. The globular structure of the carborane binding moiety and its hydrophobic character qualify it as an ideal recognition site to form stable inclusion complexes with macrocyclic host molecules in aqueous solution. The measured binding affinities for the carborane derivatives were in the millimolar range (K-a=10(3)-10(4)m(-1)) with differently sized CDs, and preferential binding to beta-CD.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemistry - A European Journal

  • ISSN

    0947-6539

  • e-ISSN

  • Volume of the periodical

    24

  • Issue of the periodical within the volume

    49

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    12970-12975

  • UT code for WoS article

    000443382500028

  • EID of the result in the Scopus database

    2-s2.0-85052611031