Macropolyhedral Nickelaboranes from the Metal-Assisted Fusion of KB9H14
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F19%3A00509827" target="_blank" >RIV/61388980:_____/19:00509827 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02116" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02116</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.9b02116" target="_blank" >10.1021/acs.inorgchem.9b02116</a>
Alternative languages
Result language
angličtina
Original language name
Macropolyhedral Nickelaboranes from the Metal-Assisted Fusion of KB9H14
Original language description
The reaction of K[arachno-B9H14] with [NiCl2(dppe)] produces four new 19-vertex macropolyhedral metallaboranes that result from borane cluster fusion: [9'-(dppe)-9'-Ni-anti-B18H20] (1) and isomeric [11'-(dppe)-11'-Ni-syn-B18H20] (2), together with the chlorine-substituted derivative of 1, [5'-Cl-9'-(dppe)-9'-Ni-anti-B18H19] (3), and the 18-vertex cluster compound [7'-(dppe)-7'-anti-NiB17H21] (4). Two closo 10-vertex single-cluster species, [1-(dppe)-1-closo-NiB9H7Cl2] (5) and [1-(dppe)-1-closo-NiB9H7Cl(OH)] (6), were also isolated from the reaction. The production of the metalated syn-octadecaborane isomer 2 from the fusion of two arachno-nonaborate clusters is the first such case to be observed, in all other reported cases fusion has resulted in products with the anti-octadecaboranyl bis-nido configuration.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA18-20286S" target="_blank" >GA18-20286S: Boron Hydride Cluster Lasers: Understanding the Chemical and Structural Factors that Determine the Photophysics of anti-B18H22 and its Derivatives</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
58
Issue of the periodical within the volume
19
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
13258-13267
UT code for WoS article
000489676400087
EID of the result in the Scopus database
2-s2.0-85072993485