Tetrazine-Based Metal-Organic Frameworks as Scaffolds for Post-Synthetic Modification by Click Reaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F20%3A00520591" target="_blank" >RIV/61388980:_____/20:00520591 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0306450" target="_blank" >http://hdl.handle.net/11104/0306450</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201901230" target="_blank" >10.1002/ejic.201901230</a>
Alternative languages
Result language
angličtina
Original language name
Tetrazine-Based Metal-Organic Frameworks as Scaffolds for Post-Synthetic Modification by Click Reaction
Original language description
Metal-organic frameworks are one of the most active research fields today. Despite the progress in recent years, synthesis of highly porous structures bearing functional groups for specific applications remains a challenge. Here, we describe synthesis of Zr(IV) and Hf(IV)-based tetrazine containing metalorganic frameworks, ZrTz-68 and HfTz-68 with pore size of 2.1 nm, specific surface area up to 4217 m2 g -1, and a UiO-68 topology. The synthesis can be done on a multi-gram scale from inexpensive linker 4,4’-(1,2,4,5-tetrazine-3,6-diyl)dibenzoic acid (H2TzDB). Moreover, because of the л-conjugated tetrazine groups these MOFs can be easily post-synthetically modified by a “click” reaction maintaining the crystallinity of the framework. Due to the diversity of “clickable” substituents, this strategy represents highly versatile tool for a wide range of applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2020
Issue of the periodical within the volume
5
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
461-466
UT code for WoS article
000508451900001
EID of the result in the Scopus database
2-s2.0-85078680299