Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F20%3A00521907" target="_blank" >RIV/61388980:_____/20:00521907 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0306453" target="_blank" >http://hdl.handle.net/11104/0306453</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2020.121132" target="_blank" >10.1016/j.jorganchem.2020.121132</a>
Alternative languages
Result language
angličtina
Original language name
Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route
Original language description
Series of closo-decaborate (NH4)2[B10H10] derivatives were prepared by their direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH4+ present as a counter cation. The reactions were carried out under mild conditions in open air at reflux in the absence of any subsidiary catalyst. The yield and degree of substitution of the derivatives depend on the duration of the reaction and the applied temperature. Derivatives were characterized by NMR, MS-ESI and TLC. The study elaborates the proposed mechanism of the nucleophilic substitution on [B10H10]2– by illustrating the assistance of an initiator to catalyze the reaction.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
910
Issue of the periodical within the volume
MAR
Country of publishing house
CH - SWITZERLAND
Number of pages
6
Pages from-to
121132
UT code for WoS article
000514191300003
EID of the result in the Scopus database
2-s2.0-85078656375