Structurally rigidified cobalt bis(dicarbollide) derivatives, a chiral platform for labelling of biomolecules and new materials

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F22%3A00554162" target="_blank" >RIV/61388980:_____/22:00554162 - isvavai.cz</a>
Alternative codes found
RIV/68081707:_____/22:00554162 RIV/00216208:11160/22:10450945
Result on the web
<a href="https://doi.org/10.1039/D1CC06979A" target="_blank" >https://doi.org/10.1039/D1CC06979A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1cc06979a" target="_blank" >10.1039/d1cc06979a</a>

Result language
angličtina
Original language name
Structurally rigidified cobalt bis(dicarbollide) derivatives, a chiral platform for labelling of biomolecules and new materials
Original language description
We report the difunctional modification of an anionic cobalta bis(dicarbollide)(1(-)) cluster with a B(8,8')-oxygen bridging unit that provides structural rigidity and an organic alkylazide substituent(s) on the carbon atoms of the metallacarborane cage. These ions present a good binding motif for incorporation into organic molecules using Huisgen-Sharpless (2+3) cycloaddition reactions. In addition, the compounds are chiral, as verified by separation of enantiomers using HPLC on chiral stationary phases (CSPs) and provide a high electrochemical peak in the window located outside of typical signals of biomolecules.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)