Fibrillation of Pristine 2D Materials by 2D-Confined Electrolytes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F24%3A00584850" target="_blank" >RIV/61388980:_____/24:00584850 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0354846" target="_blank" >https://hdl.handle.net/11104/0354846</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adfm.202315038" target="_blank" >10.1002/adfm.202315038</a>
Alternative languages
Result language
angličtina
Original language name
Fibrillation of Pristine 2D Materials by 2D-Confined Electrolytes
Original language description
2D materials are solid microscopic flakes with a-few-Angstrom thickness possessing some of the largest surface-to-volume ratios known. Altering their conformation state from a flat flake to a scroll or fiber offers a synergistic association of properties arising from 2D and 1D nanomaterials. However, a combination of the long-range electrostatic and short-range solvation forces produces an interlayer repulsion that has to be overcome, making scrolling 2D materials without disrupting the pristine structure a challenging task. Herein, a facile method is presented to alter the 2D materials' inter-layer interactions by confining organic salts onto their basal area, forming 2D-confined electrolytes. The confined electrolytes produce local charge inhomogeneities, which can conjugate across the interlayer gap, binding the two surfaces. This allows the 2D-confined electrolytes to behave as polyelectrolytes within a higher dimensional order (2D> 1D) and form robust nanofibers with distinct electronic properties. The method is not material-specific and the resulting fibers are tightly bound even though the crystal structure of the basal plane remains unaltered.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Functional Materials
ISSN
1616-301X
e-ISSN
1616-3028
Volume of the periodical
34
Issue of the periodical within the volume
29
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
2315038
UT code for WoS article
001186210500001
EID of the result in the Scopus database
2-s2.0-85187932825