New palladium complexes with 8-hydroxyquinolines prepared by a ligand exchange during NMR experiments
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F25%3A00637940" target="_blank" >RIV/61388980:_____/25:00637940 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/25:00637940
Result on the web
<a href="https://doi.org/10.1002/ejic.202500141" target="_blank" >https://doi.org/10.1002/ejic.202500141</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.202500141" target="_blank" >10.1002/ejic.202500141</a>
Alternative languages
Result language
angličtina
Original language name
New palladium complexes with 8-hydroxyquinolines prepared by a ligand exchange during NMR experiments
Original language description
Palladium(II) complexes with derivatives of 8-hydroxyquinoline (HXQ) of composition NH2(CH3)2[PdCl2(XQ)], where HXQ is 5-nitro-7-iodo-8-hydroxyquinoline (HNIQ) (1a), 5-nitro-7-bromo-8-hydroxyquinoline (HNBrQ) (2a), 5-iodo-7-bromo-8-hydroxyquinoline (HIBrQ) (3a), and 5-chloro-7-bromo-8-hydroxyquinoline (HClBrQ) (4a), were prepared. Upon their dissolution in DMSO, a series of [PdCl(DMSO)(XQ)] (1b-4b) and [Pd(XQ)2] (1c-4c) complexes is prepared as a consequence of a ligand exchange. The composition of the complexes is elucidated by infrared and NMR spectroscopy and elemental and single-crystal X-ray structure analysis. Moreover, crystal structures of the ligands HClBrQ and HIBrQ are solved.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
1099-0682
Volume of the periodical
28
Issue of the periodical within the volume
21
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
e202500141
UT code for WoS article
001517472100001
EID of the result in the Scopus database
2-s2.0-105004342586