[Ag62S12(CBT)32]4+: A 2.2 nm two-electron superatomic carborane-thiolated silver nanocluster exhibiting multilayer charge separation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F25%3A00639915" target="_blank" >RIV/61388980:_____/25:00639915 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/25:00639915
Result on the web
<a href="https://doi.org/10.1021/acsnano.5c11836" target="_blank" >https://doi.org/10.1021/acsnano.5c11836</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsnano.5c11836" target="_blank" >10.1021/acsnano.5c11836</a>

Result language
angličtina
Original language name
[Ag62S12(CBT)32]4+: A 2.2 nm two-electron superatomic carborane-thiolated silver nanocluster exhibiting multilayer charge separation
Original language description
Investigating large metal nanoclusters decorated with three-dimensional molecular cages, with complete structural characterization, is challenging, however, their detailed understanding is important to study electronic confinement and associated properties. We have structurally resolved a nearly spherical 2.2 nm silver cluster with the molecular composition [Ag62S12(CBT)32]4+, altogether having 842 atoms, solely protected with meta-carborane-thiolates (CBTs). This is the largest nanocluster with carborane-based molecular cages reported so far.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/LTAIN19152" target="_blank" >LTAIN19152: Carborane-protected metal nanoclusters: A new family of materials with atomic precision</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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