Carboranedithiols: Building Blocks for Self-Assembled Monolayers on Copper Surfaces

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389005%3A_____%2F12%3A00382471" target="_blank" >RIV/61389005:_____/12:00382471 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/12:00382471 RIV/67985882:_____/12:00382471 RIV/61388955:_____/12:00382471

Result on the web

<a href="http://dx.doi.org/10.1021/la302334x" target="_blank" >http://dx.doi.org/10.1021/la302334x</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/la302334x" target="_blank" >10.1021/la302334x</a>

Result language

angličtina

Original language name

Carboranedithiols: Building Blocks for Self-Assembled Monolayers on Copper Surfaces

Original language description

Two different positional isomers of 1,2-dicarba-closo-dodecaboranedithiols, 1,2-(HS)(2)-1,2-C2B10H10 (1) and 9,12-(HS)2-1,2-C2B10H10 (2), have been investigated as cluster building blocks for self-assembled monolayers (SAMs) on copper surfaces. These twoisomers represent a convenient system in which the attachment of SH groups at different positions on the skeleton affects their acidic character and thus also determines their reactivity with a copper surface. Isomer 1 exhibited etching of polycrystalline Cu films, and a detailed investigation of the experimental conditions showed that both the acidic character of SH groups and the presence of oxygen at the copper surface play crucial roles in how the surface reaction proceeds: whether toward a self-assembled monolayer or toward copper film etching. We found that each positional isomer requires completely different conditions for the preparation of a SAM on copper surfaces Both isomers exhibited high capacity to remove oxygen atoms fro

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Langmuir

ISSN

0743-7463

e-ISSN

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Volume of the periodical

28

Issue of the periodical within the volume

34

Country of publishing house

US - UNITED STATES

Number of pages

9

Pages from-to

12518-12526

UT code for WoS article

000307988700013

EID of the result in the Scopus database

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