Hydroboration of Graphene Oxide: Towards Stoichiometric Graphol and Hydroxygraphane
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389005%3A_____%2F15%3A00444989" target="_blank" >RIV/61389005:_____/15:00444989 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/15:43899772
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201406168" target="_blank" >http://dx.doi.org/10.1002/chem.201406168</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201406168" target="_blank" >10.1002/chem.201406168</a>
Alternative languages
Result language
angličtina
Original language name
Hydroboration of Graphene Oxide: Towards Stoichiometric Graphol and Hydroxygraphane
Original language description
Covalently functionalized graphene materials with well-defined stoichiometric composition are of a very high importance in the research of 2D carbon material family due to their well-defined properties. Unfortunately, most of the contemporary graphene-functionalized materials do not have this kind of defined composition and, usually, the amount of heteroatoms bonded to graphene framework is in the range of 1-10at.%. Herein, we show that by a well-established hydroboration reaction chain, which introduces BH2 groups into the graphene oxide structure, followed by H2O2 or CF3COOH treatment as source of OH or H, we can obtain highly hydroxylated compounds of precisely defined composition with a general formula (C1O0.78H0.75)(n), which we named graphol andhighly hydroxylated graphane (C-1(OH)(0.51)H-0.14)(n), respectively. These highly functionalized materials with an accurately defined composition are highly important for the field of graphene derivatives. The enhanced electrochemical per
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
—
Volume of the periodical
21
Issue of the periodical within the volume
22
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
8130-8136
UT code for WoS article
000354651300023
EID of the result in the Scopus database
2-s2.0-84929337870