Low temperature magneto-structural transitions in Mn3Ni20P6
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389005%3A_____%2F16%3A00459215" target="_blank" >RIV/61389005:_____/16:00459215 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jssc.2016.02.028" target="_blank" >http://dx.doi.org/10.1016/j.jssc.2016.02.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jssc.2016.02.028" target="_blank" >10.1016/j.jssc.2016.02.028</a>
Alternative languages
Result language
angličtina
Original language name
Low temperature magneto-structural transitions in Mn3Ni20P6
Original language description
X-ray and neutron powder diffraction has been used to determine the crystal and magnetic structure of Mn3Ni20P6. The crystal structure can be described as cubic with space group Fm (3) over barm (225) without any nuclear phase transformation within studied temperature interval from room temperature down to 4 K. The magnetic structure of Mn3Ni20P6 is complex with two independent magnetic positions for the Mn atoms and the compound passes three successive magnetic phase transitions during cooling. At 30 K the spins of the Mn atoms on the Wyckoff 4a site (Mn1) order to form a primitive cubic anti ferromagnetic structure with propagation vector k=(0 0 1). Between 29 and 26 K the Mn atoms on the Wyckoff 8c site (Mn2) order independently on already ordered Mn1 magnetic structure forming a commensurate antiferromagnetic structure with propagation vector k= (0 0 1/2) and below 26 K, both Mn positions order to form an incommensurate helical structure with propagation vector k=(0 0 similar to 0.45). Magnetization vs. temperature curve of Mn3Ni20P6 shows a steep increase indicating some magnetic ordering below 230 K and a sharp field dependent anomaly in a narrow temperature range around 30 K.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LM2011019" target="_blank" >LM2011019: CANAM (Center of Accelerators and Nuclear Analytical Methods)</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Solid State Chemistry
ISSN
0022-4596
e-ISSN
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Volume of the periodical
237
Issue of the periodical within the volume
MAY
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
343-348
UT code for WoS article
000373661100047
EID of the result in the Scopus database
2-s2.0-84962268845