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Low temperature magneto-structural transitions in Mn3Ni20P6

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389005%3A_____%2F16%3A00459215" target="_blank" >RIV/61389005:_____/16:00459215 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jssc.2016.02.028" target="_blank" >http://dx.doi.org/10.1016/j.jssc.2016.02.028</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jssc.2016.02.028" target="_blank" >10.1016/j.jssc.2016.02.028</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Low temperature magneto-structural transitions in Mn3Ni20P6

  • Original language description

    X-ray and neutron powder diffraction has been used to determine the crystal and magnetic structure of Mn3Ni20P6. The crystal structure can be described as cubic with space group Fm (3) over barm (225) without any nuclear phase transformation within studied temperature interval from room temperature down to 4 K. The magnetic structure of Mn3Ni20P6 is complex with two independent magnetic positions for the Mn atoms and the compound passes three successive magnetic phase transitions during cooling. At 30 K the spins of the Mn atoms on the Wyckoff 4a site (Mn1) order to form a primitive cubic anti ferromagnetic structure with propagation vector k=(0 0 1). Between 29 and 26 K the Mn atoms on the Wyckoff 8c site (Mn2) order independently on already ordered Mn1 magnetic structure forming a commensurate antiferromagnetic structure with propagation vector k= (0 0 1/2) and below 26 K, both Mn positions order to form an incommensurate helical structure with propagation vector k=(0 0 similar to 0.45). Magnetization vs. temperature curve of Mn3Ni20P6 shows a steep increase indicating some magnetic ordering below 230 K and a sharp field dependent anomaly in a narrow temperature range around 30 K.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LM2011019" target="_blank" >LM2011019: CANAM (Center of Accelerators and Nuclear Analytical Methods)</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Solid State Chemistry

  • ISSN

    0022-4596

  • e-ISSN

  • Volume of the periodical

    237

  • Issue of the periodical within the volume

    MAY

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    343-348

  • UT code for WoS article

    000373661100047

  • EID of the result in the Scopus database

    2-s2.0-84962268845