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High surface stability of magnetite on bi-layer Fe3O4/Fe/MgO(0 0 1) films under 1 MeV Kr+ ion irradiation

Result description

We investigate the stability of the bi-layer Fe3O4/Fe(0 0 1) films grown epitaxially on MgO(0 0 1) substrates with the layer thickness in the range of 25-100 nm upon 1 MeV Kr+ ion irradiation. The layer structure and layer composition of the films before and after ion irradiation were studied by XRR, RBS and RBS-C techniques. The interdiffusion and intermixing was analyzed. No visible change in the RBS spectra was observed upon irradiation with ion fluence below 10(15) Kr cm-2. The bi-layer structure and the stoichiometric Fe3O4 layer on the surface were well preserved after Kr+ ion irradiation at low damage levels, although the strong intermixing implied a large interfacial (FexOy) and (Fe, Mg)Oy layer respective at Fe3O4-Fe and Fe-MgO interface. The high ion fluence of 3.8 × 10(16) Kr cm-2 has induced a complete oxidization of the buffer Fe layer. Under such Kr fluence, the stoichiometry of the Fe3O4 surface layer was still preserved indicating its high stability. The entire film contains FexOy -type composition at ion fluence large than 5.0 × 10(16) Kr cm-2.

Keywords

nanosciencethin filmsurface and interface

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    High surface stability of magnetite on bi-layer Fe3O4/Fe/MgO(0 0 1) films under 1 MeV Kr+ ion irradiation

  • Original language description

    We investigate the stability of the bi-layer Fe3O4/Fe(0 0 1) films grown epitaxially on MgO(0 0 1) substrates with the layer thickness in the range of 25-100 nm upon 1 MeV Kr+ ion irradiation. The layer structure and layer composition of the films before and after ion irradiation were studied by XRR, RBS and RBS-C techniques. The interdiffusion and intermixing was analyzed. No visible change in the RBS spectra was observed upon irradiation with ion fluence below 10(15) Kr cm-2. The bi-layer structure and the stoichiometric Fe3O4 layer on the surface were well preserved after Kr+ ion irradiation at low damage levels, although the strong intermixing implied a large interfacial (FexOy) and (Fe, Mg)Oy layer respective at Fe3O4-Fe and Fe-MgO interface. The high ion fluence of 3.8 × 10(16) Kr cm-2 has induced a complete oxidization of the buffer Fe layer. Under such Kr fluence, the stoichiometry of the Fe3O4 surface layer was still preserved indicating its high stability. The entire film contains FexOy -type composition at ion fluence large than 5.0 × 10(16) Kr cm-2.

  • Czech name

  • Czech description

Classification

  • Type

    Jost - Miscellaneous article in a specialist periodical

  • CEP classification

  • OECD FORD branch

    10304 - Nuclear physics

Result continuities

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Advances in Natural Sciences: Nanoscience and Nanotechnology

  • ISSN

    2043-6262

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    VN - VIET NAM

  • Number of pages

    9

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database