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Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389005%3A_____%2F99%3A49020110" target="_blank" >RIV/61389005:_____/99:49020110 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses.

  • Original language description

    Glasses from Ge.sub.x./sub.As.sub.40-x./sub.Se.sub.60./sub., Ge.sub.x./sub.Sb.sub.40-x./sub.S.sub.60./sub. and Ge.sub.x./sub.Sb.sub40-x./sub.Se.sub.60./sub. families have been investigated by neutron diffraction. The well expressed 'first sharp diffraction peak' of the neutron spectra at Q= 10- 14 nm.sub.-1./sub. has been explained by a pseudo-binary model of the structure of studied chalcogenide glasses. The amplitude of this interference maximum increases with Ge-content in all investigated samples. Experimental radial distribution functions show that the basic structural units, GeS(Se).sub.4./sub. tetrahedra and As(Sb)S.sub.3./sub. or As(Sb)Se.sub.3./sub. pyramids persist in glassy state for the whole range of studied compositions. Crystal-like model distribution functions have been used to describe the short-range order observed. A shortening of heteropolar bonds in S-containing glasses as well as an increase of heteropolar bonds length in Se-containing glasses has been found.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GV202%2F97%2FK038" target="_blank" >GV202/97/K038: Centre for fundamental and applied neutron research</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    1999

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Materials Science

  • ISSN

    0022-2461

  • e-ISSN

  • Volume of the periodical

    34

  • Issue of the periodical within the volume

    N/A

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    3669-3676

  • UT code for WoS article

  • EID of the result in the Scopus database