Cyclization and self-organization in polymerization of trialkoxysilanes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F01%3A55010307" target="_blank" >RIV/61389013:_____/01:55010307 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Cyclization and self-organization in polymerization of trialkoxysilanes.

Original language description

Sol-gel polymerization of organotrialkoxysilanes and formation of silsesquioxane (SSQO) structures was followed using SEC, 29 Si NMR, SAXS and WAXS. A strong tendency to build-up of polyhedral cyclic oligomers 'cages' grows with increasing size of the organic substituent. Due to incompatibility of the polyhedral SSQO framework and pendant organic chains, microphase separation takes place and spontaneous self-organization occurs.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CD - Macromolecular chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Macromolecules

ISSN

0024-9297

e-ISSN

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Volume of the periodical

34

Issue of the periodical within the volume

20

Country of publishing house

US - UNITED STATES

Number of pages

11

Pages from-to

6904-6914

UT code for WoS article

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EID of the result in the Scopus database

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