All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Chemical oxidative polymerization of anilinium sulfate versus aniline: Theory and experiment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F08%3A00306832" target="_blank" >RIV/61389013:_____/08:00306832 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Chemical oxidative polymerization of anilinium sulfate versus aniline: Theory and experiment

  • Original language description

    The mechanism of the oxidative polymerization of anilinium sulfate with ammonium peroxydisulfate in aqueous medium has been studied by the AM1 and MNDO-PM3 semi-empirical quantum chemical methods combined with the MM2 molecular mechanics force-field method and conductor-like screening model (COSMO) of solvation. It has been compared with the aniline nitrenium cation which is the main reactive electrophilic species generated in the initiation phase.

  • Czech name

    Chemická oxidativní polymerace síranového aniontu versus anilinu: Teorie a experiment

  • Czech description

    Mechanismus oxidativní polymerace aniliniového kaniontu peroxydvojsíranem amonným ve vodném prostředí byl studován pomocí AM1 a MNDO-PM3 semi-empirickou kvantově-chemickou metodami v kombinaci s MM2 molekulárně-mechanickou force-field metodou a conductor-like screening modelem (COSMO) rozpustnosti. Mechanismus byl porovnán s nitreniovým kationtem, který je hlavním reaktivním elektrofilním produktem generovaným v počáteční fázi oxidace.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F08%2F0686" target="_blank" >GA203/08/0686: The spectroscopic study of the evolution of polyaniline nanostructures</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Synthetic Metals

  • ISSN

    0379-6779

  • e-ISSN

  • Volume of the periodical

    158

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    12

  • Pages from-to

    200-211

  • UT code for WoS article

  • EID of the result in the Scopus database