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Morphology of undeformed and deformed polyethylene lamellar crystals

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F10%3A00349870" target="_blank" >RIV/61389013:_____/10:00349870 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Morphology of undeformed and deformed polyethylene lamellar crystals

  • Original language description

    Morphology of undeformed polyethylene crystals obtained by high pressure crystallization was investigated by SEM. The etching procedure was refined to reveal defected sites of lamellae in addition to differentiation of crystalline and amorphous phases. From 1 to 3 screw dislocations with large Burgers vector per 1 ?m2 of lamellae basal planes were detected. High pressure-crystallized polyethylene samples were deformed plastically by uniaxial compression and studied by SEM and AFM. When the deformation is interrupted dislocations are arrested within the crystals. Plastically deformed polyethylene crystals are highly defected ? the density of dislocations was approximated as 1016 m2. However, deformed crystal melting temperature is nearly unaffected while the heat of melting is slightly reduced, yet only in thin crystals. It suggests that the arrested dislocations contribute more to the surface energy of lamellae basal planes rather than to the bulk energy of polyethylene crystals.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP205%2F10%2F0348" target="_blank" >GAP205/10/0348: Sandwich nanocomposites: preparation, nucleation effects, electrical properties.</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer

  • ISSN

    0032-3861

  • e-ISSN

  • Volume of the periodical

    51

  • Issue of the periodical within the volume

    24

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

  • UT code for WoS article

    000284248100017

  • EID of the result in the Scopus database