Oxidation of aniline in dopant-free template-free dilute reaction media
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F11%3A00358890" target="_blank" >RIV/61389013:_____/11:00358890 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.matchemphys.2011.02.047" target="_blank" >http://dx.doi.org/10.1016/j.matchemphys.2011.02.047</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.matchemphys.2011.02.047" target="_blank" >10.1016/j.matchemphys.2011.02.047</a>
Alternative languages
Result language
angličtina
Original language name
Oxidation of aniline in dopant-free template-free dilute reaction media
Original language description
The oxidation of aniline with ammonium peroxydisulfate in water without added acid was studied in dilute reaction media. The new nanostructured nonconducting polyaniline sulfate/hydrogen sulfate, synthesized by dilute dopant-free template-free falling-pHmethod, consists of network of nanorods and nanogranules. The molecular structure of polyaniline, investigated by the elemental analysis, FTIR, Raman, UV?Vis and EPR spectroscopies, was found to be significantly different in comparison with the structure of the nanostructured PANI sulfate/hydrogen sulfate prepared by dopant-free template-free falling-pH method in concentrated aqueous aniline solutions. The mechanism of the formation of nanostructured polyaniline under dopant-free template-free dilute reaction conditions is discussed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F08%2F0686" target="_blank" >GA203/08/0686: The spectroscopic study of the evolution of polyaniline nanostructures</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Materials Chemistry and Physics
ISSN
0254-0584
e-ISSN
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Volume of the periodical
127
Issue of the periodical within the volume
3
Country of publishing house
CN - CHINA
Number of pages
10
Pages from-to
501-510
UT code for WoS article
000290504300015
EID of the result in the Scopus database
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