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Experimental and DFT study on the complexation of Ba2+ with beauvericin

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F13%3A00389444" target="_blank" >RIV/61389013:_____/13:00389444 - isvavai.cz</a>

  • Alternative codes found

    RIV/60460709:41330/13:61040 RIV/60461373:22340/13:43895015

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s10967-012-2107-1" target="_blank" >http://dx.doi.org/10.1007/s10967-012-2107-1</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10967-012-2107-1" target="_blank" >10.1007/s10967-012-2107-1</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Experimental and DFT study on the complexation of Ba2+ with beauvericin

  • Original language description

    From extraction experiments and ?-activity measurements, the exchange extraction constant corresponding to the equilibrium Ba2+(aq) + 1.Sr2+(nb) and 1.Ba2+(nb) + Sr2+(aq) taking place in the two-phase water?nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (Ba2+, 1.Sr2+) = 1.2 0.1. Further, the stability constant of the beauvericin?barium complex (abbrev. 1.Ba2+) in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log?nb (1.Ba2+) = 9.5 0.2. Finally, by using quantum mechanical DFT calculations, the most probable structure of the 1.Ba2+ complex species was predicted.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP205%2F10%2F2280" target="_blank" >GAP205/10/2280: Photogeneration and charge transport in molecular semiconductors for organic photovoltaics</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Radioanalytical and Nuclear Chemistry

  • ISSN

    0236-5731

  • e-ISSN

  • Volume of the periodical

    295

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    HU - HUNGARY

  • Number of pages

    5

  • Pages from-to

    1887-1891

  • UT code for WoS article

    000314895400039

  • EID of the result in the Scopus database