Towards directional assembly of hierarchical structures: aniline oligomers as the model precursors

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F13%3A00390940" target="_blank" >RIV/61389013:_____/13:00390940 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c3nr00145h" target="_blank" >http://dx.doi.org/10.1039/c3nr00145h</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c3nr00145h" target="_blank" >10.1039/c3nr00145h</a>

Result language
angličtina
Original language name
Towards directional assembly of hierarchical structures: aniline oligomers as the model precursors
Original language description
Hierarchical architectures attract a large number of scientists and engineers because of their unique physicochemical properties compared with bulk materials and their precursors. It is believed that intermolecular interactions play a key role in the formation of these hierarchical architectures. However, the principle of coordination of various intermolecular interactions in the self-assembly process is not clear. Here, an aniline oligomer is used as a model brick to study the formation process of well-defined hierarchical architectures, and the directional growth mechanism is proposed. It is assumed that aniline oligomer molecules are asymmetric, and driven by intermolecular attractive forces to aggregate in various manners. Combined with the interactions between the aniline oligomer and molecules from the medium, three-dimensional assemblies, flower-like and urchin-like microspheres, can be formed. The variability and complexity of morphologies produced in the process was analyzed a
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP205%2F12%2F0911" target="_blank" >GAP205/12/0911: Aniline oligomers and their role in the formation of polyaniline nanostructures –spectroscopic analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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