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Characterizing crystal disorder of trospium chloride: a comprehensive, 13C CP/MAS NMR, DSC, FTIR, and XRPD study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F13%3A00391506" target="_blank" >RIV/61389013:_____/13:00391506 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/13:43895363

  • Result on the web

    <a href="http://dx.doi.org/10.1002/jps.23457" target="_blank" >http://dx.doi.org/10.1002/jps.23457</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/jps.23457" target="_blank" >10.1002/jps.23457</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Characterizing crystal disorder of trospium chloride: a comprehensive, 13C CP/MAS NMR, DSC, FTIR, and XRPD study

  • Original language description

    Analysis of 13C cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC), Fourier transform infrared (FTIR), and X-ray powder diffraction data of trospium chloride (TCl) products crystallized from different mixtures of water?ethanol [?(EtOH) = 0.5?1.0] at various temperatures (0°C, 20°C) and initial concentrations (saturated solution, 30%?50% excess of solvent) revealed extensive structural variability of TCl. Although 13C CP/MAS NMR spectra indicated broad variety of structural phases arising from molecular disorder, temperature-modulated DSC identified presence of two distinct components in the products. FTIR spectra revealed alterations in the hydrogen bonding network (ionic hydrogenbond formation), whereas the X-ray diffraction reflected unchanged unit cell parameters. These results were explained by a two-component character of TCl products in which a dominant polymorphic form is accompanied by partly separated nan

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    FR - Pharmacology and apothecary chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GPP106%2F11%2FP426" target="_blank" >GPP106/11/P426: Enhancement of bioavailability of insoluble pharmaceutical substances by the action of polymeric matrix</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Pharmaceutical Sciences

  • ISSN

    0022-3549

  • e-ISSN

  • Volume of the periodical

    102

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    14

  • Pages from-to

    1235-1248

  • UT code for WoS article

    000315723700009

  • EID of the result in the Scopus database