Thermodynamic and kinetic aspects of coassembly of PEO-PMAA block copolymer and DPCl surfactants into ordered nanoparticles in aqueous solutions studied by ITC, NMR, and time-resolved SAXS techniques
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F13%3A00391524" target="_blank" >RIV/61389013:_____/13:00391524 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ma302503w" target="_blank" >http://dx.doi.org/10.1021/ma302503w</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ma302503w" target="_blank" >10.1021/ma302503w</a>
Alternative languages
Result language
angličtina
Original language name
Thermodynamic and kinetic aspects of coassembly of PEO-PMAA block copolymer and DPCl surfactants into ordered nanoparticles in aqueous solutions studied by ITC, NMR, and time-resolved SAXS techniques
Original language description
The electrostatic coassembly of a block copolymer polyelectrolyte poly(ethylene oxide-block-poly-(methacrylic acid), PEO705PMAA476, and oppositely charged surfactant, N-dodecylpyridinium chloride (DPCl), has been investigated by a combination of isothermal titration calorimetry (ITC), spin-echo NMR spectroscopy, and time-resolved SAXS measurements. The results reveal new insight into the thermodynamic and kinetic behavior of the self-assembling system. The most important finding obtained by stopped-flowtime-resolved SAXS measurements concerns the surprisingly high rate of processes of creation of structurally ordered cores of self-assembled surfactantpolyelectrolyte nanoparticles (<50 ms).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecules
ISSN
0024-9297
e-ISSN
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Volume of the periodical
46
Issue of the periodical within the volume
6
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
2172-2181
UT code for WoS article
000316847500015
EID of the result in the Scopus database
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