Hydrogen-bonding versus .pi.-.pi. stacking in the design of organic semiconductors: from dyes to oligomers

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00442968" target="_blank" >RIV/61389013:_____/15:00442968 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010" target="_blank" >http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010" target="_blank" >10.1016/j.progpolymsci.2014.10.010</a>

Result language

angličtina

Original language name

Hydrogen-bonding versus .pi.-.pi. stacking in the design of organic semiconductors: from dyes to oligomers

Original language description

This review discusses some general aspects of the highly directional intermolecular interactions in organic solids, followed by an overview of ?-conjugated systems exhibiting directional preference in the intermolecular connection and demonstrating enhanced energy and/or charge carrier transfer. As examples, ?small dyes and pigments, ?intermediate-sized N-heteroacenes, and ?large hydrogen-bonded oligomers are considered. In all of these systems the intermolecular interactions between polarized peripheries of the ?-conjugated moieties ensure a preferential direction in the molecular packing. The most important among these interactions are hydrogen bonds (both strong and weak). As demonstrated recently, hydrogen bonding represents a dominant attractive force even for molecules with different polarization of the ?-conjugated aromatic or heterocyclic moieties, considered to be the most favorable condition for ?face-to-face orientation (??? stacking). The solid-state anisotropy, most likely

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CD - Macromolecular chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Progress in Polymer Science

ISSN

0079-6700

e-ISSN

—

Volume of the periodical

43

Issue of the periodical within the volume

April

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

15

Pages from-to

33-47

UT code for WoS article

000353007600002

EID of the result in the Scopus database

2-s2.0-84939943916