Effect of layered silicates and reactive compatibilization on structure and properties of melt-drawn HDPE/PA6 microfibrillar composites
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F16%3A00459326" target="_blank" >RIV/61389013:_____/16:00459326 - isvavai.cz</a>
Alternative codes found
RIV/68407700:21220/16:00234427
Result on the web
<a href="http://dx.doi.org/10.1007/s00289-015-1570-6" target="_blank" >http://dx.doi.org/10.1007/s00289-015-1570-6</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s00289-015-1570-6" target="_blank" >10.1007/s00289-015-1570-6</a>
Alternative languages
Result language
angličtina
Original language name
Effect of layered silicates and reactive compatibilization on structure and properties of melt-drawn HDPE/PA6 microfibrillar composites
Original language description
Microfibrillar composites (MFCs) of HDPE matrix with PA6 reinforcing fibrils formed in situ by melt drawing were modified by ethylene/glycidyl methacrylate copolymer (PEGMA) and addition of layered silicates using different mixing protocols. The goal was enhancement of adhesion between fibrils and matrix, their reinforcement by clay, and evaluation of the effect of clay on the MFC morphology, especially the fibril dimensions. Improved mechanical properties, including toughness, were found in the case of pre-blending Cloisite 15A (C15) with both polymeric components. Pre-blending of Cloisite C30B (C30) in PA6 is effective at low draw ratios only, whereas simultaneous addition of both clays leads to significant worsening of properties. In many cases, low stiffness increase indicates existence of clay-induced controversial effects which may eliminate reinforcement induced by fibrils and clay. The results indicate that these effects are significantly affected by the extent and course of clay migration between polymer phases during extrusion-mixing and melt drawing. Possible explanation of affecting the properties due to low-modulus interface supported by finite element analysis (FEA) is presented.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
JI - Composite materials
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA13-15255S" target="_blank" >GA13-15255S: Self reinforced polymer-polymer composites upgraded by nanofillers of various geometry</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polymer Bulletin
ISSN
0170-0839
e-ISSN
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Volume of the periodical
73
Issue of the periodical within the volume
6
Country of publishing house
DE - GERMANY
Number of pages
16
Pages from-to
1673-1688
UT code for WoS article
000376248900013
EID of the result in the Scopus database
2-s2.0-84948162885