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Effect of layered silicates and reactive compatibilization on structure and properties of melt-drawn HDPE/PA6 microfibrillar composites

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F16%3A00459326" target="_blank" >RIV/61389013:_____/16:00459326 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21220/16:00234427

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s00289-015-1570-6" target="_blank" >http://dx.doi.org/10.1007/s00289-015-1570-6</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00289-015-1570-6" target="_blank" >10.1007/s00289-015-1570-6</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of layered silicates and reactive compatibilization on structure and properties of melt-drawn HDPE/PA6 microfibrillar composites

  • Original language description

    Microfibrillar composites (MFCs) of HDPE matrix with PA6 reinforcing fibrils formed in situ by melt drawing were modified by ethylene/glycidyl methacrylate copolymer (PEGMA) and addition of layered silicates using different mixing protocols. The goal was enhancement of adhesion between fibrils and matrix, their reinforcement by clay, and evaluation of the effect of clay on the MFC morphology, especially the fibril dimensions. Improved mechanical properties, including toughness, were found in the case of pre-blending Cloisite 15A (C15) with both polymeric components. Pre-blending of Cloisite C30B (C30) in PA6 is effective at low draw ratios only, whereas simultaneous addition of both clays leads to significant worsening of properties. In many cases, low stiffness increase indicates existence of clay-induced controversial effects which may eliminate reinforcement induced by fibrils and clay. The results indicate that these effects are significantly affected by the extent and course of clay migration between polymer phases during extrusion-mixing and melt drawing. Possible explanation of affecting the properties due to low-modulus interface supported by finite element analysis (FEA) is presented.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JI - Composite materials

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA13-15255S" target="_blank" >GA13-15255S: Self reinforced polymer-polymer composites upgraded by nanofillers of various geometry</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer Bulletin

  • ISSN

    0170-0839

  • e-ISSN

  • Volume of the periodical

    73

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    16

  • Pages from-to

    1673-1688

  • UT code for WoS article

    000376248900013

  • EID of the result in the Scopus database

    2-s2.0-84948162885