Influence of ionic liquid-modified LDH on microwave-assisted polymerization of .epsilon.-caprolactone

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F16%3A00462149" target="_blank" >RIV/61389013:_____/16:00462149 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/16:00462149
Result on the web
<a href="http://dx.doi.org/10.1016/j.polymer.2016.08.014" target="_blank" >http://dx.doi.org/10.1016/j.polymer.2016.08.014</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.polymer.2016.08.014" target="_blank" >10.1016/j.polymer.2016.08.014</a>

Result language
angličtina
Original language name
Influence of ionic liquid-modified LDH on microwave-assisted polymerization of .epsilon.-caprolactone
Original language description
The study reported herein describes multifunctional effect of layered double hydroxide (LDH) modified with phosphonium-based ionic liquids (IL) containing phosphinate, carboxylate and phosphate anions on progress of ring-opening polymerization of ε-caprolactone under microwave irradiation. The extent of IL-modification had a crucial effect on the exfoliation of LDH. The non-modified LDH was able to catalyse the ring-opening polymerization of ε-caprolactone with polymer yield 89% but provided only micro-composite material. On the contrary, LDH with intercalated IL-anions promoted exfoliation of LDH after only 3 min of microwave irradiation. The developed process is fast, environmentally-friendly (solvent-free) and adaptable to various polymer matrices, since a broad variety of IL-anions might be applied.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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