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Thermally treated polyaniline/polybenzimidazole blend membranes: structural changes and gas transport properties

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F17%3A00474722" target="_blank" >RIV/61389013:_____/17:00474722 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.memsci.2017.04.062" target="_blank" >http://dx.doi.org/10.1016/j.memsci.2017.04.062</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.memsci.2017.04.062" target="_blank" >10.1016/j.memsci.2017.04.062</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermally treated polyaniline/polybenzimidazole blend membranes: structural changes and gas transport properties

  • Original language description

    Polyaniline/polybenzimidazole (PANI/PBI) blend membranes with various ratios of PANI/PBI were prepared by the solution casting method. The resulting free-standing membranes were subsequently doped with hydrochloric acid. In the next step, the membranes were heated up to 600 °C in an inert nitrogen atmosphere. FTIR spectroscopy and Raman scattering show the conversion of the blend to a nitrogen-containing carbon-like material. The permeability and sorption properties with respect to H2, O2, N2, CH4, and CO2 were determined. The separation qualities of the thermally treated PANI/PBI blend membranes significantly exceed those of non-thermally treated membranes. The permeation properties show a strong dependence on the PANI concentration in the blend and on its doping. The best separation performance for H2/N2, CO2/N2, and CO2/CH4 is obtained with the thermally treated undoped PANI/PBI 20/80 blend membrane.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Membrane Science

  • ISSN

    0376-7388

  • e-ISSN

  • Volume of the periodical

    537

  • Issue of the periodical within the volume

    1 September

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    315-322

  • UT code for WoS article

    000402508600031

  • EID of the result in the Scopus database

    2-s2.0-85019194123