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Development and testing of a novel catalyst-coated membrane with platinum-free catalysts for alkaline water electrolysis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00505870" target="_blank" >RIV/61389013:_____/19:00505870 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/19:43918432

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0360319919318853?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0360319919318853?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ijhydene.2019.05.054" target="_blank" >10.1016/j.ijhydene.2019.05.054</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Development and testing of a novel catalyst-coated membrane with platinum-free catalysts for alkaline water electrolysis

  • Original language description

    A stable, platinum-free catalyst-coated anion-exchange membrane with a promising performance for alkaline water electrolysis as an energy conversion technology was prepared and tested. A hot plate spraying technique used to deposit electrodes 35 or 120 μm thick on the surface of an anion-selective polymer electrolyte membrane. These thicknesses of 35 and 120 μm corresponding to the catalyst load of 2.5 and 10 mg cm−2. The platinum free catalysts based on NiCo2O4 for anode and NiFe2O4 for cathode were used together with anion selective polymer binder in the catalyst/binder ratio equal to 9:1. The performance of the prepared membrane-electrode assembly was verified under conditions of alkaline water electrolysis using different concentrations of liquid electrolyte ranging from 1 to 15 wt% KOH. The electrolyser performance was compared to a cell utilizing a catalyst-coated Ni foam as the electrodes. The prepared membrane-electrode assembly stability at a current load of 0.25 A cm−2 was verified by a 72-hour electrolysis test. The results of the experiments indicated the possibility of a significant reduction of the catalyst loading compared to a catalyst-coated substrate approach.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Hydrogen Energy

  • ISSN

    0360-3199

  • e-ISSN

  • Volume of the periodical

    44

  • Issue of the periodical within the volume

    33

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

    17493-17504

  • UT code for WoS article

    000476964900006

  • EID of the result in the Scopus database

    2-s2.0-85066270196