The first products of aniline oxidation - SERS spectroelectrochemistry
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00507818" target="_blank" >RIV/61389013:_____/19:00507818 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/slct.201802878" target="_blank" >https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/slct.201802878</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/slct.201802878" target="_blank" >10.1002/slct.201802878</a>
Alternative languages
Result language
angličtina
Original language name
The first products of aniline oxidation - SERS spectroelectrochemistry
Original language description
There are different opinions on the first products of aniline oxidation throughout the scientific community. While electrochemists basically accept only linear oligomers with repeating units joint in para positions, chemists have proposed formation of various branched and polycyclic oligomers. It was also suggested that one of these structures, N‐phenyl‐phenazinium cation, is responsible for the adherence of polyaniline films to substrates. In this work, a surface enhanced Raman spectroscopic and spectroelectrochemical analysis of the species adsorbed onto gold surface in aniline‐containing solution at pH 1 and 5 is presented. The influence of the pH value on the oligomer structure is declared. The results are discussed in the context of linear and branched/phenazine‐like aniline oligomers.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10404 - Polymer science
Result continuities
Project
<a href="/en/project/GJ18-01924Y" target="_blank" >GJ18-01924Y: Vibrational spectroscopy and spectroelectrochemistry of the first products formed during conducting polymer preparation</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemistrySelect
ISSN
2365-6549
e-ISSN
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Volume of the periodical
4
Issue of the periodical within the volume
30
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
8847-8854
UT code for WoS article
000480775500016
EID of the result in the Scopus database
2-s2.0-85070699273