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Surfactants and amino acids in the control of nanotubular morphology of polypyrrole and their effect on the conductivity

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00522423" target="_blank" >RIV/61389013:_____/20:00522423 - isvavai.cz</a>

  • Result on the web

    <a href="https://link.springer.com/article/10.1007%2Fs00396-020-04607-6" target="_blank" >https://link.springer.com/article/10.1007%2Fs00396-020-04607-6</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00396-020-04607-6" target="_blank" >10.1007/s00396-020-04607-6</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Surfactants and amino acids in the control of nanotubular morphology of polypyrrole and their effect on the conductivity

  • Original language description

    Polypyrrole nanotubes were prepared by the oxidation of pyrrole in aqueous solutions of methyl orange and in the presence of 1–5 wt% of surface-active additives, surfactants, or amino acids. Three types of additives – anionic, non-ionic, and cationic – have been tested in the control of polypyrrole morphology and conductivity. The morphology of nanotubes was little dependent on surfactant type but the changes in size and aspect ratios were more pronounced with amino acids. Except for anionic surfactant, bis(2-ethylhexyl) sulfosuccinate, which behaved indifferently, all additives reduced the conductivity of polypyrrole, some even by four orders of magnitude. Based on FTIR spectroscopy, it is proposed that the hydrophobic interactions and/or hydrogen bonding between the additives and growing polypyrrole chains play the important role in reducing chain ordering, while the ionic interactions have limited effect.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GA17-04109S" target="_blank" >GA17-04109S: Study of the materials based on the conducting polymers by advanced spectroscopic methods</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Colloid and Polymer Science

  • ISSN

    0303-402X

  • e-ISSN

  • Volume of the periodical

    298

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    319-325

  • UT code for WoS article

    000514975600011

  • EID of the result in the Scopus database

    2-s2.0-85079415650