Method of preparation of soluble PEDOT: self‐polymerization of EDOT without oxidant at room temperature
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00532368" target="_blank" >RIV/61389013:_____/20:00532368 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/20:10424694
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/10.1002/macp.202000219" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/macp.202000219</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/macp.202000219" target="_blank" >10.1002/macp.202000219</a>
Alternative languages
Result language
angličtina
Original language name
Method of preparation of soluble PEDOT: self‐polymerization of EDOT without oxidant at room temperature
Original language description
The preparation of soluble conducting polymers proceeds by the chemical oxidation method in the presence of water‐soluble polyelectrolytes. Among conducting polymers, polyethylene‐(3,4‐dioxythiophene) (PEDOT) is the most investigated due to its intrinsic properties. In this work, for the first time a simple method of ethylene‐(3,4‐dioxythiophne) self‐polymerization without applying any oxidant and with the formation of PEDOT solution at room temperature with a yield of 100% is presented. This PEDOT solution could be deposited on many desirable surfaces (by simple evaporation of the solvent) for various applications from photovoltaic cell to pseudocapacitors. Moreover, it is discovered that the self‐polymerization method does not produce byproducts, which makes the method environmentally friendly. The effect of light and different acids is explored. Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy (XPS), and Raman spectroscopy confirm the formation of PEDOT by the self‐polymerization method. Moreover, this method provides a way to obtain and study individual PEDOT chains. The self‐polymerization method may be applied for the preparation of other conducting polymers.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10404 - Polymer science
Result continuities
Project
<a href="/en/project/GA19-04859S" target="_blank" >GA19-04859S: Interaction of conducting polymers with organic dyes: Principles and consequences</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecular Chemistry and Physics
ISSN
1022-1352
e-ISSN
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Volume of the periodical
221
Issue of the periodical within the volume
18
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
1-11
UT code for WoS article
000562131600001
EID of the result in the Scopus database
2-s2.0-85089784809