Gallium species incorporated into MOF structure: insight into the formation of a 3D polycrystalline gallium-imidazole framework
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00532774" target="_blank" >RIV/61389013:_____/20:00532774 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/20:00532774 RIV/60461373:22320/20:43920301 RIV/60461373:22810/20:43920301 RIV/00216224:14740/20:00121450
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01563" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01563</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.0c01563" target="_blank" >10.1021/acs.inorgchem.0c01563</a>
Alternative languages
Result language
angličtina
Original language name
Gallium species incorporated into MOF structure: insight into the formation of a 3D polycrystalline gallium-imidazole framework
Original language description
The formation of a polycrystalline 3D gallium–imidazole framework (MOF) was closely studied in three steps using ssNMR, XRPD, and TGA. In all steps, the reaction products show relatively high temperature stability up to 500 °C. The final product was examined by structural analysis using NMR crystallography combined with TG and BET analyses, which enabled a detailed characterization of the polycrystalline MOF system on the atomic-resolution level. 71Ga ssNMR spectra provided valuable structural information on the coexistence of several distinct gallium species, including a tunable liquid phase. Moreover, using an NMR crystallography approach, two structurally asymmetric units of Ga(Im6)6– incorporated into the thermally stable polycrystalline 3D matrix were identified. Prepared polycrystalline MOF material with polymorphic gallium species is promising for use in catalytic processes.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
<a href="/en/project/GA19-05259S" target="_blank" >GA19-05259S: Combining advanced ultra-wideline ssNMR spectroscopy with XRPD and Computational Chemistry to study organo-metallic and frameworks materials</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
19
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
13933-13941
UT code for WoS article
000580381700016
EID of the result in the Scopus database
2-s2.0-85092058344